Vogler, Arnd (2016) Nickel(II) complexes as triplet emitters? IL phosphorescence of Ni(II)(binap)Cl-2 under ambient conditions. INORGANIC CHEMISTRY COMMUNICATIONS, 65. pp. 39-40. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
The complexes M(II)(binap)Cl-2 with M = Ni and Pd and binap = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl show an IL phosphorescence in the solid state under ambient conditions. The nickel(II) complex is a unique example of a triplet emitter. Generally, any triplet emission of Ni(II) complexes is quenched by non-emissive low-energy LF excited states. In the case of the binap complex, the LF states are apparently located at energies well above the IL triplet. (C) 2016 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | OPTICAL-PROPERTIES; EXCITED-STATES; INTRALIGAND; LUMINESCENCE; PORPHYRINS; LIGANDS; Nickel; Palladium; Binap; Luminescence; Triplet emitter |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Mar 2019 08:29 |
| Last Modified: | 12 Mar 2019 08:29 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2353 |
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