Muehldorf, Bernd and Wolf, Robert (2016) C-H Photooxygenation of Alkyl Benzenes Catalyzed by Riboflavin Tetraacetate and a Non-Heme Iron Catalyst. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55 (1). pp. 427-430. ISSN 1433-7851, 1521-3773
Full text not available from this repository. (Request a copy)Abstract
A mixture of the photocatalyst riboflavin tetraacetate (RFT) and the biomimetic non-heme iron complex [Fe(TPA)-(MeCN) (2)](ClO4)(2) (TPA=tris(2-pyridylmethyl)amine) efficiently catalyzes the visible-light-driven aerobic oxidation of alkyl benzenes to ketones and carboxylic acids. An RFTcatalyzed photocycle and the independent action of the iron complex as a catalyst for H2O2 disproportionation and alkyl benzene oxygenation ensure high yields and selectivities.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOINDUCED ELECTRON-TRANSFER; OLEFIN CIS-DIHYDROXYLATION; PHOTOCATALYTIC OXYGENATION; VISIBLE-LIGHT; BOND OXIDATION; FLAVIN ANALOG; COMPLEXES; HYDROCARBONS; ACTIVATION; REACTIVITY; flavins; iron; oxygenation; photocatalysis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Mar 2019 08:27 |
| Last Modified: | 15 Mar 2019 08:27 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2558 |
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