Visible light induced redox neutral fragmentation of 1,2-diol derivatives

Chen, Kang and Schwarz, Johanna and Karl, Tobias A. and Chatterjee, Anamitra and Koenig, Burkhard (2019) Visible light induced redox neutral fragmentation of 1,2-diol derivatives. CHEMICAL COMMUNICATIONS, 55 (87). pp. 13144-13147. ISSN 1359-7345, 1364-548X

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Abstract

A homogeneous, redox-neutral photo fragmentation of diol derivatives was developed. Under photo/hydrogen atom transfer (HAT) dual catalysis, diol derivatives such as lignin model compounds and diol monoesters undergo selective beta C(sp(3))-O bond cleavage to afford ketones, phenols and acids effectively.

Item Type: Article
Uncontrolled Keywords: O BOND-CLEAVAGE; C-H BONDS; PHOTOCATALYTIC OXIDATION; DIRECT ARYLATION; LIGNIN; PHOTOREDOX; DEGRADATION; ALCOHOLS; HYDROGENOLYSIS; DEPOLYMERIZATION;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 24 Mar 2020 10:46
Last Modified: 24 Mar 2020 10:46
URI: https://pred.uni-regensburg.de/id/eprint/25842

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