CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation

Kumar, Amit and Daw, Prosenjit and Espinosa-Jalapa, Noel Angel and Leitus, Gregory and Shimon, Linda J. W. and Benn-David, Yehoshoa and Milstein, David (2019) CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation. DALTON TRANSACTIONS, 48 (39). pp. 14580-14584. ISSN 1477-9226, 1477-9234

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Abstract

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal-ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

Item Type: Article
Uncontrolled Keywords: LOW-PRESSURE HYDROGENATION; DEFINED IRON CATALYST; CARBON-DIOXIDE; BOND ACTIVATION; REDUCTION; METHANOL; FORMATE; AMINES; BICARBONATES; TEMPERATURE;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 25 Mar 2020 08:56
Last Modified: 25 Mar 2020 08:56
URI: https://pred.uni-regensburg.de/id/eprint/25986

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