Maedl, Eric and Peresypkina, Eugenia and Timoshkin, Alexey Y. and Scheer, Manfred (2016) Triple-decker sandwich complexes with a bent cyclo-P-5 middle-deck. CHEMICAL COMMUNICATIONS, 52 (83). pp. 12298-12301. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
New types of triple-decker complexes with an organo-substituted P-5 middle-deck were synthesized by the reaction of [Cp*Fe(eta(4)-P5R)](-) (1a: R = CH2SiMe3; 1b: R = NMe2) with halogeno-bridged transition metal dimers [Cp ''' MX](2) (M= Cr, Fe, Co, Ni; X = Cl, Br). By oxidation of [(Cp*Fe)(Cp ''' Co)(mu,eta(4:3)-P5CH2SiMe3)] 2a with [Cp2Fe][PF6], the cationic complex [(Cp*Fe)(Cp ''' Co)(mu,eta(5:4)-P5CH2SiMe3)](+) was isolated. The electronic structure of the synthesized complexes was elucidated by DFT calculations.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | LIGAND; FERROCENE; PENTAPHOSPHAFERROCENE; IRON; PHOSPHORUS; DERIVATIVES; CHEMISTRY; COORDINATION; POLYMERS; MOLECULE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Mar 2019 14:47 |
| Last Modified: | 13 Mar 2019 14:47 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2636 |
Actions (login required)
 |
View Item |
