Moussa, M. Elsayed and Attenberger, B. and Peresypkina, E. V. and Fleischmann, M. and Balazs, G. and Scheer, M. (2016) Facile synthesis of one-dimensional organometallic-organic hybrid polymers based on a diphosphorus complex and flexible bipyridyl linkers. CHEMICAL COMMUNICATIONS, 52 (65). pp. 10004-10007. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
The selective synthesis of a series of new "ladderlike'' onedimensional organometallic-organic hybrid polymers is shown. The polymers are obtained from the reaction of the diphosphorus ligand complex [Cp2Mo2(CO)(4)(eta(2)-P-2)] with the copper salt [Cu(CH3CN)(4)]BF4 in the presence of flexible organic bipyridyl linkers in high selectivity. This unique behaviour is supported by DFT calculations.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | POROUS COORDINATION POLYMERS; N-DONOR LIGANDS; CRYSTAL-STRUCTURES; SUPRAMOLECULAR ISOMERISM; MAGNETIC-PROPERTIES; ANIONS SYNTHESES; BUILDING-BLOCKS; FRAMEWORKS; METALLACYCLES; CHEMISTRY; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Mar 2019 09:30 |
| Last Modified: | 14 Mar 2019 09:30 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2662 |
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