Sahoo, Basudev and Bellotti, Peter and Julia-Hernandez, Francisco and Meng, Qing-Yuan and Crespi, Stefano and Koenig, Burkhard and Martin, Ruben (2019) Site-Selective, Remote sp(3) C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis. CHEMISTRY-A EUROPEAN JOURNAL, 25 (38). pp. 9001-9005. ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
A photoinduced carboxylation of alkyl halides with CO2 at remote sp(3) C-H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | VISIBLE-LIGHT PHOTOREDOX; CARBON-DIOXIDE; ALKYL BROMIDES; ARYL HALIDES; CO2; STYRENES; BONDS; HYDROCARBOXYLATION; COMPLEX; ACIDS; carbon dioxide; carboxylation; chain-walking; nickel; photocatalysis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 Apr 2020 08:35 |
| Last Modified: | 07 Apr 2020 08:35 |
| URI: | https://pred.uni-regensburg.de/id/eprint/26651 |
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