Fischer, Theresa and Bamberger, Julia and Mancheno, Olga Garcia (2016) Asymmetric nucleophilic dearomatization of diazarenes by anion-binding catalysis. ORGANIC & BIOMOLECULAR CHEMISTRY, 14 (24). pp. 5794-5802. ISSN 1477-0520, 1477-0539
Full text not available from this repository. (Request a copy)Abstract
The first anion-binding organocatalyzed enantioselective Reissert-type dearomatization of diazarenes has been developed. This reaction represents a synthetic challenge since diazarenes have various reactive sites. The use of a chiral tetrakistriazole as a C-H-based hydrogen-donor catalyst allowed the straightforward highly regio- and enantioselective synthesis of a variety of chiral diazaheterocycles.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | N-ACYLIMINIUM IONS; MANNICH REACTION; LEWIS-BASE; ALDEHYDES; ISOQUINOLINES; DERIVATIVES; INHIBITORS; TRIAZOLES; AMINATION; PYRIDINES; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Olga Garcia Mancheño |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Mar 2019 08:00 |
| Last Modified: | 22 Mar 2019 08:05 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2686 |
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