Hoidn, Christian M. and Wolf, Robert (2016) Reaction of a 2,4,6-triphenylphosphinine ferrate anion with electrophiles: a new route to phosphacyclohexadienyl complexes. DALTON TRANSACTIONS, 45 (21). pp. 8875-8884. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
A novel, versatile route to phosphorus-and carbon-substituted eta(5)-phosphacyclohexadienyl complexes was developed. Reaction of the anionic 2,4,6-triphenylphosphinine iron complex [K([18]crown-6)(thf)(2)][(CpFe)-Fe-star(PC5Ph3H2)] (1) with selected main group element electrophiles afforded the new complexes [(CpFe)-Fe-star(2-endo-H-PC5Ph3H2)] (endo-3), [(CpFe)-Fe-star(2-exo-H-PC5Ph3H2)] (exo-3), [(CpFe)-Fe-star(1-Me-PC5Ph3H2)] (4), [(CpFe)-Fe-star(1-Me3Si-PC5Ph3H2)] (5), [(CpFe)-Fe-star(1-PPh2-PC5Ph3H2)] (6) and [(CpFe)-Fe-star(2-BCat-PC5Ph3H2)] (7, BCat = 2-benzo[d][1,3,2]dioxaborol-2-yl). Initial attack of the electrophile at phosphorus was observed, leading to a P-substitued phosphinine ligand. A subsequent rearragement occured in some cases, resulting in C-substituted phosphinine complexes endo-3, exo-3 and 7. The new complexes were characterized by H-1, P-31{H-1}, and C-13{H-1} NMR spectroscopy, UV-vis spectroscopy and elemental analysis; their molecular structures were determined by X-ray crystallography.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | X-RAY CRYSTAL; SPS-BASED RHODIUM(I); BOND COVALENT RADII; DFT CALCULATIONS; CORRELATION-ENERGY; IRON COMPLEXES; BASIS-SETS; DENSITY; EXCHANGE; LIGAND; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 18 Mar 2019 13:17 |
| Last Modified: | 18 Mar 2019 13:17 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2689 |
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