Visible Light-Induced Regioselective Cycloaddition of Benzoyl Azides and Alkenes To Yield Oxazolines

Bellotti, Peter and Brocus, Julien and El Orf, Fatima and Selkti, Mohamed and Koenig, Burkhard and Belmont, Philippe and Brachet, Etienne (2019) Visible Light-Induced Regioselective Cycloaddition of Benzoyl Azides and Alkenes To Yield Oxazolines. JOURNAL OF ORGANIC CHEMISTRY, 84 (10). pp. 6278-6285. ISSN 0022-3263, 1520-6904

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Abstract

Visible light catalysis allows the regioselective synthesis of oxazolines in high yields. The mild photosensitized manifold leverages the intermolecular formation of oxazolines with a wide functional group tolerance on both benzoyl azides and alkenes partners. Mechanistic investigations suggest the sensitization of the azide moiety as the key activation step.

Item Type: Article
Uncontrolled Keywords: OLEFIN AZIRIDINATION; ACYL AZIDES; PHOTOREDOX; PHOTOCHEMISTRY; ACYLNITRENES; GENERATION; CATALYSIS; INDOLE; ACID;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Apr 2020 11:31
Last Modified: 14 Apr 2020 11:31
URI: https://pred.uni-regensburg.de/id/eprint/27003

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