Schiller, Jana and Alegre-Requena, Juan V. and Marques-Lopez, Eugenia and Herrera, Raquel P. and Casanovas, Jordi and Aleman, Carlos and Diaz Diaz, David (2016) Self-assembled fibrillar networks of a multifaceted chiral squaramide: supramolecular multistimuli-responsive alcogels. SOFT MATTER, 12 (19). pp. 4361-4374. ISSN 1744-683X, 1744-6848
Full text not available from this repository. (Request a copy)Abstract
Chiral N, N'-disubstituted squaramide 1 has been found to undergo self-assembly in a variety of alcoholic solvents at low concentrations leading to the formation of novel nanostructured supramolecular alcogels. The gels responded to thermal, mechanical, optical and chemical stimuli. Solubility studies, gelation ability tests and computer modeling of a series of structurally related squaramides proved the existence of a unique combination of non-covalent molecular interactions and favorable hydrophobic/hydrophilic balance in 1 that drive the anisotropic growth of alcogel networks. The results have also revealed a remarkable effect of ultrasound on both the gelation kinetics and the properties of the alcogels.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MOLECULAR-WEIGHT GELATORS; MASS ORGANIC GELATORS; GEL TRANSFORMATION; GELATION; ORGANOGELS; TRANSITION; RECOGNITION; DERIVATIVES; KINETICS; BINDING; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. David Díaz Díaz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Mar 2019 14:06 |
| Last Modified: | 15 Mar 2019 14:06 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2702 |
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