Pelties, Stefan and Ehlers, Andreas W. and Wolf, Robert (2016) Insertion of phenyl isothiocyanate into a P-P bond of a nickel-substituted bicyclo[1.1.0]tetraphosphabutane. CHEMICAL COMMUNICATIONS, 52 (39). pp. 6601-6604. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
A new reaction mode for bicyclo[1.1.0]tetraphosphabutanes is reported. The C=S and C=N bonds of phenyl isothiocyanate reversibly insert into a P-P bond of [{CpNi(IMes)}(2)(mu-eta(1):eta(1)-P-4)] (1(Mes), IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene), forming isomers 2a and 2b. X-ray crystallography and P-31{H-1} NMR spectroscopy revealed similar bicyclo[3.1.0]heterohexane structures for these compounds.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL-COMPLEXES; WHITE PHOSPHORUS; P-4 ACTIVATION; 1,2,3-TRIPNICTOLIDE ANIONS; FUNCTIONALIZED LIGANDS; CAGE COMPOUNDS; LEWIS-ACID; CHEMISTRY; TETRAHEDRON; REACTIVITY; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Mar 2019 10:13 |
| Last Modified: | 15 Mar 2019 10:13 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2706 |
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