Vogler, Arnd and Bodensteiner, Michael (2019) Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)(2)(dithiooxamide)]Cl (phpy=2-(2-pyridyl)phenyl). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 74 (5). pp. 405-408. ISSN 0932-0776, 1865-7117
Full text not available from this repository. (Request a copy)Abstract
The salt [Rh(III)(phpy)(2) (dtoxa)](C)l with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at lambda(max) = 607 nm with phi = 10(-3) and tau = 3.7 ns in CH2Cl2.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | DITHIOOXAMIDE COMPLEXES; LUMINESCENCE; crystal structure; dithiooxamide; photoluminescence; rhodium(III) |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 Apr 2020 08:08 |
| Last Modified: | 09 Apr 2020 08:08 |
| URI: | https://pred.uni-regensburg.de/id/eprint/27109 |
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