Wimmer, Alexander and Koenig, Burkhard (2019) N-Arylation of NH-Sulfoximines via Dual Nickel Photocatalysis. ORGANIC LETTERS, 21 (8). pp. 2740-2744. ISSN 1523-7060, 1523-7052
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The pharmaceutically underexplored sulfoximine moiety has emerged as a potentially active pharmaceutical ingredient. We developed a scalable synthetic route to N-arylated sulfoximines from the respective "free" NH-sulfoximines and bromoarenes. Our strategy is based on a dual nickel photocatalytic approach, is applicable for a broad scope of substrates, and exhibits a highly functional group tolerance. In addition, we could demonstrate that other sulfoximidoyl derivatives like sulfonimidamides and sulfinamides proceed smoothly under the developed reaction conditions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ARYL IODIDES; LIGANDS; PHOTOREDOX; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Apr 2020 07:08 |
| Last Modified: | 15 Apr 2020 07:08 |
| URI: | https://pred.uni-regensburg.de/id/eprint/27153 |
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