Tiefenthaler, Susanne and Korber, Nikolaus and Gaertner, Stefanie (2019) Synthesis of the Tetragonal Phase of Zintl's NaTl and Its Structure Determination from Powder Diffraction Data. MATERIALS, 12 (8): 1356. ISSN 1996-1944,
Full text not available from this repository. (Request a copy)Abstract
A tetragonal distortion of the long-time known NaTl structure at 298 K was observed in different experimental setups, including Zintl's original procedure of reducing Tl(I)-iodide by sodium liquid ammonia solutions. The powder diffraction pattern obtained by the high temperature synthesis using classical solid-state techniques allowed a model-independent unambiguous structure solution and refinement of tetragonal distorted NaTl (Rp = 0.0179, wRp = 0.0246, R = 0.0477, wR = 0.0527, GooF = 1.24).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | METALS; ANNOUNCEMENT; CONSTRUCTION; AMMONIA; ALLOYS; KTL; Zintl phase; NaTl; ammonia; X-ray powder diffraction |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Apr 2020 08:49 |
| Last Modified: | 15 Apr 2020 08:49 |
| URI: | https://pred.uni-regensburg.de/id/eprint/27187 |
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