Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

Yatham, Veera Reddy and Bellotti, Peter and Koenig, Burkhard (2019) Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis. CHEMICAL COMMUNICATIONS, 55 (24). pp. 3489-3492. ISSN 1359-7345, 1364-548X

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Abstract

We report the cerium photocatalyzed radical decarboxylative hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-catalyzed decarboxylation of carboxylic acids.

Item Type: Article
Uncontrolled Keywords: PHOTOREDOX CATALYSIS; FUNCTIONALIZATION; COMPLEXES; OXIDATION;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 15 Apr 2020 10:31
Last Modified: 15 Apr 2020 10:31
URI: https://pred.uni-regensburg.de/id/eprint/27339

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