Synthesis and characterisation of alpha-carboxynitrobenzyl photocaged l-aspartates for applications in time-resolved structural biology

Zaitsev-Doyle, John J. and Puchert, Anke and Pfeifer, Yannik and Yan, Hao and Yorke, Briony A. and Mueller-Werkmeister, Henrike M. and Uetrecht, Charlotte and Rehbein, Julia and Huse, Nils and Pearson, Arwen R. and Sans, Marta (2019) Synthesis and characterisation of alpha-carboxynitrobenzyl photocaged l-aspartates for applications in time-resolved structural biology. RSC ADVANCES, 9 (15). pp. 8695-8699. ISSN 2046-2069,

Full text not available from this repository. (Request a copy)

Abstract

We report a new synthetic route to a series of a-carboxynitrobenzyl photocaged L-aspartates for application in time-resolved structural biology. The resulting compounds were characterised in terms of UV/Vis absorption properties, aqueous solubility and stability, and photocleavage rates (tau = ms to ms) and quantum yields (phi = 0.05 to 0.14).

Item Type: Article
Uncontrolled Keywords: REACTION-MECHANISMS; PROMOTING MOTIONS; PROTEIN; PHOTOLYSIS; DYNAMICS;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 27 Apr 2020 05:31
Last Modified: 27 Apr 2020 05:31
URI: https://pred.uni-regensburg.de/id/eprint/27363

Actions (login required)

View Item View Item