Visible-light mediated C-C bond cleavage of 1,2-diols to carbonyls by cerium-photocatalysis

Schwarz, Johanna and Koenig, Burkhard (2019) Visible-light mediated C-C bond cleavage of 1,2-diols to carbonyls by cerium-photocatalysis. CHEMICAL COMMUNICATIONS, 55 (4). pp. 486-488. ISSN 1359-7345, 1364-548X

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Abstract

We describe a photocatalytic method for the cleavage of vicinal diols to aldehydes and ketones. The reaction is catalyzed by blue light and a cerium-catalyst and the scope includes aryl as well as alkyl substituted diols. The simple protocol which works under air and at room temperature enables the valorization of abundant diols.

Item Type: Article
Uncontrolled Keywords: OXIDATIVE CLEAVAGE; VICINAL DIOLS; ALDEHYDES;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 21 Apr 2020 04:57
Last Modified: 21 Apr 2020 04:57
URI: https://pred.uni-regensburg.de/id/eprint/27726

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