Gas sensing properties of electrically conductive Cu(I) compounds at elevated temperatures

Wolpert, Benjamin and Wolfbeis, Otto S. and Mirsky, Vladimir M. (2009) Gas sensing properties of electrically conductive Cu(I) compounds at elevated temperatures. SENSORS AND ACTUATORS B-CHEMICAL, 142 (2). pp. 446-450. ISSN 0925-4005,

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Abstract

Changes in the electrical conductance at 240 degrees C of a number of copper(I) compounds including CuI, CuBr, Cu2Te, Cu12Sb4S13, (CuI)(2)P-14, and of NiO were measured following the exposure to the gases ammonia, nitrogen dioxide. nitrous oxide, carbon monoxide, carbon dioxide, and propane. Analytical sensitivity and kinetic parameters were compared quantitatively. The high diversity of sensitivity patterns makes these compounds promising candidates for use in sensor arrays. Principal component analysis of the data obtained with a virtual sensor array enabled highly selective sensing of five of the six analytes studied using only two principle components. Activation energies of the charge transport in the materials were determined. (C) 2009 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: ROOM-TEMPERATURE; SENSOR ARRAY; THIN-FILMS; POLYMERS; TRANSPORT; DETECTOR; Gas sensor; Ammonia sensor; Conductometric sensor; Sensor array; Copper(I); High-temperature sensing
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Antje J. Bäumner, formerly Prof. Wolfbeis)
Depositing User: Dr. Gernot Deinzer
Date Deposited: 02 Sep 2020 05:50
Last Modified: 02 Sep 2020 05:50
URI: https://pred.uni-regensburg.de/id/eprint/28143

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