Glycosylated nervogenic acid derivatives from Liparis condylobulbon (Reichb.f.) leaves

Slapetova, Tereza and Smejkal, Karel and Innocenti, Gabbriella and Dall'Acqua, Stefano and Heilmann, Joerg and Babula, Petr and Hamzova, Eva and Zemlicka, Milan (2009) Glycosylated nervogenic acid derivatives from Liparis condylobulbon (Reichb.f.) leaves. CARBOHYDRATE RESEARCH, 344 (13). pp. 1770-1774. ISSN 0008-6215, 1873-426X

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Abstract

Three new nervogenic acid glycosides, 1-O-alpha-L-rhamnopyranosyl 3,5-bis(3-methyl-but-2-enyl)-4-O-[alpha-L-rhamnopyranosyl-(l -> 2)-beta-D-glucopyranosyl]-benzoate, 3,5-bis(3-methyl-but-2-enyl)-4-O-[alpha-L-rhamnopyranosyl-(1 -> 2)-beta-D-glucopyranosyl]-benzoic acid, and bis{3,5-bis(3-methyl-but-2-enyl)-4-O-[alpha-L-rhamnopyranosyl-(1 -> 2)-beta-D-glucopyranosyl]-benzoyl} 1,2-O-beta-D-glucopyranose, which we named condobulbo-sides A-C, were isolated from a methanol extract of the leaves of Liparis condylobulbon together with an apigenin C-glycoside, schaftoside. Their structures were established on the basis of spectral techniques, namely, UV, IR, HR-MS spectroscopy, both 1D and 2D NMR experiments, and chemical reactions. (C) 2009 Elsevier Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: PALUDOSA L OK; ORCHIDACEAE ALKALOIDS; CAPILLARY GLC; MONOSACCHARIDES; CONFIGURATION; Liparis condylobulbon; Orchidaceae; Nervogenic acid; Glycosides
Subjects: 600 Technology > 615 Pharmacy
Divisions: Chemistry and Pharmacy > Institute of Pharmacy > Pharmaceutical Biology (Prof. Heilmann)
Depositing User: Dr. Gernot Deinzer
Date Deposited: 07 Sep 2020 08:23
Last Modified: 07 Sep 2020 08:23
URI: https://pred.uni-regensburg.de/id/eprint/28413

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