Gehrtz, Paul H. and Hirschbeck, Vera and Ciszek, Benjamin and Fleischer, Ivana (2016) Carbonylations of Alkenes in the Total Synthesis of Natural Compounds. SYNTHESIS-STUTTGART, 48 (11). pp. 1573-1596. ISSN 0039-7881, 1437-210X
Full text not available from this repository. (Request a copy)Abstract
The goal of this review is to highlight the applications of carbonylation reactions of alkenes in the total synthesis of natural compounds. These highly atom-economic reactions, which are known for their industrial applications, constitute attractive synthetic methodologies for the selective construction of carbonyl compounds. We aimed at the selection of recent methodologically attractive syntheses where carbonylations were applied as key steps. In addition, a few examples of the related carbonylation of allenes are shown. 1 Introduction 2 Hydroformylation 3 Hydroaminomethylation and Related Tandem Hydroformylation Reactions 4 Reppe Carbonylation 5 Allylic Carbonylation 6 Oxidative Carbonylation 7 Pauson-Khand Reaction 8 Summary and Outlook
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PAUSON-KHAND REACTION; PALLADIUM-CATALYZED CARBONYLATION; ENANTIOSELECTIVE TOTAL-SYNTHESIS; BOND-FORMING HYDROGENATION; ASYMMETRIC TOTAL-SYNTHESIS; REGIOSELECTIVE HYDROFORMYLATION; TETRAHYDROPYRAN SYNTHESIS; ASTERISK-CARBONYLIERUNG; ORGANOCOBALT COMPLEXES; HOMOGENEOUS CATALYSIS; total synthesis; alkenes; hydroformylation; carbonylation; Pauson-Khand reaction |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Ivana Fleischer |
| Depositing User: | Petra Gürster |
| Date Deposited: | 02 Sep 2020 05:52 |
| Last Modified: | 02 Sep 2020 05:52 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2892 |
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