Poznyak, A. L. and Pavlovskii, V. I. and Zabel, M. (2009) Synthesis, structure, and photodecarboxylation of cobalt(III) complexes with diethylenetriamine and L-ornithine [Co(Dien)(Orn)](ClO4)(2) center dot 0.5H(2)O or DL-histidine [Co(Dien)(His)](ClO4)(2). RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 54 (5). pp. 686-691. ISSN 0036-0236, 1531-8613
Full text not available from this repository.Abstract
Mixed cobalt(III) complexes with diethylenetriamine (Dien) and a tridentate anion of L-ornithine (Orn) [Co(Dien)(His)](ClO4)(2) center dot 0.5 H2O or DL-histidine (His) [Co(Dien)(Orn)](ClO4)(2) are synthesized. According to the X-ray diffraction studies, the secondary N atom of diethylenetriamine is trans to the donor N atom of the side chain of the amino acid. Organometallic products of photodecarboxylation of the complexes are isolated by ion exchange chromatography. The electronic absorption spectra indicate that the products contain three-membered Co-C-N rings.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL COMPLEXES; CRYSTAL-STRUCTURE; PHOTOLYSIS; PRODUCTS; PERCHLORATE; SPECTRA; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 Sep 2020 09:11 |
| Last Modified: | 17 Sep 2020 09:11 |
| URI: | https://pred.uni-regensburg.de/id/eprint/29103 |
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