Kraus, Florian and Aschenbrenner, Juergen C. and Klamroth, T. and Korber, Nikolaus (2009) Hydrogen Polyphosphides P3H23- and P3H32-: Synthesis and Crystal Structure of K-3(P3H2)center dot 2.3NH(3), Rb-3(P3H2)center dot NH3, [Rb(18-crown-6)](2)(P3H3)center dot 7.5NH(3), and [Cs(18-crown-6)](2)(P3H3)center dot 7NH(3). INORGANIC CHEMISTRY, 48 (5). pp. 1911-1919. ISSN 0020-1669,
Full text not available from this repository. (Request a copy)Abstract
The incongruous solvation of polyphosphides and phosphanes or the direct reduction of white phosphorus in liquid ammonia leads to the hydrogen polyphosphides catena-dihydrogen triphosphide, P3H23-, and catena-trihydrogen triphosphide, P3H32-, in the crystalline compounds K-3(P3H2)center dot 2.3NH(3) (1), Rb-3(P3H2)center dot NH3 (2), [Rb(18-crown-6)](2)(P3H3)center dot 7.5NH(3) (3), and [Cs(18-crown-6)](2)(P3H3)center dot 7NH(3) (4).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTRON LOCALIZATION FUNCTION; CHEMICAL-BOND; AMMONIA 1/2; X-RAY; PHOSPHORUS; CHEMISTRY; TRIPHOSPHIDE; ANIONS; SPECTROSCOPY; AROMATICITY; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Sep 2020 08:38 |
| Last Modified: | 21 Sep 2020 08:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/29290 |
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