mu-Bis(diphenylarsino)methane-kappa As-2:As '-bis[chloridogold(I)]

Monkowius, Uwe and Zabel, Manfred and Yersin, Hartmut (2009) mu-Bis(diphenylarsino)methane-kappa As-2:As '-bis[chloridogold(I)]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65. M281-U526. ISSN 1600-5368,

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Abstract

The title structure, [Au2Cl2(C25H22As2)], consists of discrete molecules disposed about a crystallographic twofold axis. The Au atom exhibits a nearly linear coordination by As and Cl atoms. Au center dot center dot center dot Au interactions [3.4285 angstrom(4) angstrom] and a weak intermolecular C-H center dot center dot center dot Cl hydrogen bond are present.

Item Type: Article
Uncontrolled Keywords: CRYSTAL-STRUCTURE; GOLD COMPLEXES; DIPHOSPHINOMETHANES;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Depositing User: Dr. Gernot Deinzer
Date Deposited: 21 Sep 2020 08:42
Last Modified: 21 Sep 2020 08:42
URI: https://pred.uni-regensburg.de/id/eprint/29292

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