An Efficient Carbene-Catalyzed Access to 3,4-Dihydrocoumarins

Zeitler, Kirsten and Rose, Christopher A. (2009) An Efficient Carbene-Catalyzed Access to 3,4-Dihydrocoumarins. JOURNAL OF ORGANIC CHEMISTRY, 74 (4). pp. 1759-1762. ISSN 0022-3263,

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Abstract

Dihydrocoumarins play an important role as flavor and fragrance compounds and can be prepared efficiently from o-hydroxycinnamaldehydes in a mild, atom-economic N-heterocyclic carbene-catalyzed redox lactonization. Corresponding coumarins are accessible via a one-pot domino oxidation lactonization procedure in the presence of oxidants.

Item Type: Article
Uncontrolled Keywords: N-HETEROCYCLIC CARBENES; DIELS-ALDER REACTIONS; GAMMA-BUTYROLACTONES; ALPHA,BETA-UNSATURATED ALDEHYDES; ASYMMETRIC ORGANOCATALYSIS; STEREOSELECTIVE-SYNTHESIS; NUCLEOPHILIC CARBENES; DOMINO REACTIONS; ENANTIOSELECTIVE SYNTHESIS; CONJUGATE UMPOLUNG;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Kirsten Zeitler
Depositing User: Dr. Gernot Deinzer
Date Deposited: 05 Oct 2020 09:30
Last Modified: 05 Oct 2020 09:30
URI: https://pred.uni-regensburg.de/id/eprint/29463

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