Kunz, Werner and Testard, Fabienne and Zemb, Thomas (2009) Correspondence between Curvature, Packing Parameter, and Hydrophilic-Lipophilic Deviation Scales around the Phase-Inversion Temperature. LANGMUIR, 25 (1). pp. 112-115. ISSN 0743-7463,
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We show in this paper that three ways of characterizing "spontaneous" lateral packing of amphiphiles are equivalent: the spontaneous curvature, the molecular packing parameter, and the refined hydrophilic-lipophilic balance known as HLD (hydrophilic-lipophilic deviation). Recognition of this equivalence, with its underlying hypothesis of incompressible fluid with lowest surface energy, reinforces the single parameter bending energy expression implicit in the classical papers by Ninham and Israelachvili, as well as all the predictive models of solubilization developed as yet.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | EQUATION-OF-STATE; SURFACTANT FILMS; LIPID-BILAYERS; HOFMEISTER SERIES; MONOVALENT ANIONS; DRESSED MICELLES; MICROEMULSIONS; MICROSTRUCTURE; MIXTURES; SYSTEMS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 Oct 2020 10:45 |
| Last Modified: | 07 Oct 2020 10:45 |
| URI: | https://pred.uni-regensburg.de/id/eprint/29589 |
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