1,2,3-Triphosphole derivatives as reactive intermediates

Stubenhofer, Markus and Kuntz, Christian and Balazs, Gabor and Zabel, Manfred and Scheer, Manfred (2009) 1,2,3-Triphosphole derivatives as reactive intermediates. CHEMICAL COMMUNICATIONS (13). pp. 1745-1747. ISSN 1359-7345, 1364-548X

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Abstract

The complexes [Cp*E{W(CO)(5)}(2)] (E = P, As; Cp* = C5Me5) react with 1,2-diphosphinobenzene to give 1,2,3-triphosphole and 2-arsa-1,3-diphosphole derivatives as reactive intermediates that dimerise to polycyclic phosphorous and arsenic containing cage compounds.

Item Type: Article
Uncontrolled Keywords: DUAL SUPERMESITYL STABILIZATION; PHOSPHORUS TRIPLE BOND; TRANSITION-METAL; TRICOORDINATE PHOSPHORUS; COMPLEXES; CHEMISTRY; GROUP-15; PLANAR; LIGAND; ANION;
Subjects: 600 Technology > 660 Chemical engineering
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 12 Oct 2020 05:28
Last Modified: 12 Oct 2020 05:28
URI: https://pred.uni-regensburg.de/id/eprint/29663

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