The first thiosilicate from solution: synthesis and crystal structure of (NH4)(2)[SiS3(NH3)]center dot 2NH(3)

Meier, Martin and Korber, Nikolaus (2009) The first thiosilicate from solution: synthesis and crystal structure of (NH4)(2)[SiS3(NH3)]center dot 2NH(3). DALTON TRANSACTIONS (9). pp. 1506-1508. ISSN 1477-9226,

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Abstract

The ammonolysis of SiS2 in liquid ammonia yields crystalline (NH4)(2)[SiS3(NH3)]center dot 2NH(3), which contains [SiS3(NH3)] (2-) as a derivative of the ortho-thiosilicate anion SiS44-.

Item Type: Article
Uncontrolled Keywords: LAMELLAR TELLUROSILICATE; CHALCOGENIDES; FRAMEWORKS; SIO2; ADAMANTANE; CLUSTERS; ELEMENTS; SULFIDE; SOLIDS; PHASES;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Depositing User: Dr. Gernot Deinzer
Date Deposited: 12 Oct 2020 07:12
Last Modified: 12 Oct 2020 07:12
URI: https://pred.uni-regensburg.de/id/eprint/29705

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