Kunkely, Horst and Vogler, Arnd (2009) Excited state properties of dinaphthyl ditelluride. INORGANICA CHIMICA ACTA, 362 (1). pp. 281-283. ISSN 0020-1693, 1873-3255
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Di-1-naphthyl ditelluride (Te(2)naphthyl(2)) is characterized by two low-energy excited states. The corresponding electronic transitions nTe -> sigma(*) Te-Te and nTe -> pi(*) naphthyl CT give rise to absorptions at lambda(max) = 403 and 311 nm, respectively. In solution nTe -> sigma(*) excitation leads to the cleavage of the Te-Te bond. In contrast to Te(2)naphthyl(2) in the dissolved state the solid compound shows a luminescence (lambda(max) = 576 nm) which originates from nTe -> pi(*) naphthyl CT triplet. (c) 2008 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | DIPHENYL DITELLURIDE; ABSORPTION-SPECTRA; COMPLEXES; TRANSITIONS; CHLORIDE; Electronic spectra; Photochemistry; Phosphorescence; Luminescence; Charge transfer; Tellurium |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Oct 2020 09:40 |
| Last Modified: | 12 Oct 2020 09:40 |
| URI: | https://pred.uni-regensburg.de/id/eprint/29741 |
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