Buchner, Richard and Hefter, Glenn (2009) Interactions and dynamics in electrolyte solutions by dielectric spectroscopy. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 11 (40). pp. 8984-8999. ISSN 1463-9076
Full text not available from this repository. (Request a copy)Abstract
Despite its immense abilities to quantify many aspects of ion-ion and ion-solvent interactions, dielectric relaxation spectroscopy (DRS) has long been neglected as a tool for the investigation of the structure and dynamics of electrolyte solutions. The reasons for this are briefly discussed and it is shown that many of the difficulties associated with this technique have been overcome in recent years by technological developments. Representative applications of DRS to the investigation of ion solvation and ion association in electrolyte solutions of chemical, industrial, geochemical and biological interest, including room temperature ionic liquids and polyelectrolyte systems, are discussed. The advantages of linking DRS measurements to information obtained from other experimental techniques and from computer simulations are highlighted.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SOLVENT RELAXATION PROCESSES; TEMPERATURE IONIC LIQUIDS; HYDROGEN-BOND STRUCTURE; ALKALI-HALIDE SOLUTIONS; X-RAY-ABSORPTION; AQUEOUS-SOLUTIONS; POLYELECTROLYTE SOLUTIONS; GLASS-TRANSITION; CATIONIC SURFACTANTS; MICELLAR-SOLUTIONS |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner |
| Depositing User: | Petra Gürster |
| Date Deposited: | 22 Sep 2022 06:56 |
| Last Modified: | 22 Sep 2022 06:56 |
| URI: | https://pred.uni-regensburg.de/id/eprint/29860 |
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