Synthesis of a Bicyclic Diamine Derived from Kemp's Acid

Schmaderer, Harald and Hohenleutner, Andreas and Koenig, Burkhard (2009) Synthesis of a Bicyclic Diamine Derived from Kemp's Acid. SYNTHETIC COMMUNICATIONS, 39 (14): PII 912469. pp. 2596-2604. ISSN 0039-7911, 1532-2432

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Abstract

A bicyclic diamine with defined and stable conformation in solution was prepared from Kemp's triacid. The efficient four-step synthesis of the Boc-protected diamine requires only a single purification by column chromatography. X-ray analysis and NMR spectroscopy confirm the structure of the diamine in the solid state and in solution.

Item Type: Article
Uncontrolled Keywords: CONVERGENT FUNCTIONAL-GROUPS; ENANTIOSELECTIVE PROTONATION; CHIRAL IMIDES; AMIDE; Diamine; Kemp's triacid; piperidine
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Oct 2020 06:02
Last Modified: 14 Oct 2020 06:02
URI: https://pred.uni-regensburg.de/id/eprint/29893

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