Hoppe, Diana and Pfitzner, Arno (2009) Ring-shaped [(TiCl2)(1,3-P2S8)](2) Molecules Containing Uncommon [P2S8](2-) Anions. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 635 (12). pp. 1986-1990. ISSN 0044-2313,
Full text not available from this repository. (Request a copy)Abstract
Intensely red, moisture-sensitive crystals of [(TiCl2)(1,3-P2S8)](2) were obtained by the reaction of TiCl4 and P4S10 at room temperature. The crystal structure determination revealed molecules formally consisting of two units of the anion [1,3-P2S8](2-) connected with two [TiCl2](2+) cations resulting in the ring-shaped [(TiCl2)(1,3-P2S8)](2). The thiophosphate [1,3-P2S8](2-) forms a six-membered ring and has a rather uncommon constitution among the multitude of anionic phosphorus sulfides and selenides.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURE; TITANIUM TETRACHLORIDE; ADDITION COMPOUNDS; SULFUR PHOSPHORUS; METAL HALIDES; COORDINATION; CHEMISTRY; CHLORIDE; SELENIUM; ADDUCTS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Oct 2020 06:34 |
| Last Modified: | 14 Oct 2020 06:34 |
| URI: | https://pred.uni-regensburg.de/id/eprint/29901 |
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