Dielmann, Fabian and Merkle, Roger and Heinl, Sebastian and Scheer, Manfred (2009) New Pentaphosphaferrocenes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 64 (1). pp. 3-10. ISSN 0932-0776, 1865-7117
Full text not available from this repository. (Request a copy)Abstract
By cothermolysis of [(CpFe)-Fe-R(CO)(2)](2) [Cp-R = eta(5)-C-5(CH2Ph)(5) (Cp-bn) (1) and eta(5)-C5Me4C2H4SMe (Cp-S) (2)] With P-4 phosphorus two novel pentaphosphaferrocenes of the formula [(CpFe)-Fe-R(eta(5)-P-5)] [Cp-R = Cp-S (3), Cp-bu (4)] have been synthesised and comprehensively characterised. These two products represent the first derivatives of this class of compounds With a functionalised its well as a sterically bulky adjacent cyclopentadienyl ligand. The pentabenzylcyclopentadienyl derivative 4 its well as both of the starting materials [(CpFe)-Fe-R(CO)(2)](2) 1 and 2 have been additionally characterised by X-ray diffraction structure determinations. The pentaphosphaferrocene 4 represents in the crystal lattice highly aggregated units via intra- and intermolecular pi-stacking interactions of the phenyl rings of the Cp-bn ligand.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL-COMPLEXES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; TRIPHOSPHA-FERROCENES; WHITE PHOSPHORUS; IRON; COORDINATION; CHEMISTRY; LIGANDS; FUNCTIONALIZATION; Ferrocene; Pentabenzylcyclopentadiene Ligand; Phosphorus; Iron; Pentaphosphaferrocene |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Oct 2020 07:12 |
| Last Modified: | 14 Oct 2020 07:12 |
| URI: | https://pred.uni-regensburg.de/id/eprint/29910 |
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