Schwarz, Patrick and Wachter, Joachim and Zabel, Manfred (2008) Novel Coordination Modes for E4S3 Cage Molecules (E = P, As) in Unprecedented Quaternary As4S3(CuCl)(n) (n=1,2) Solid-State Phases. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (35). pp. 5460-5463. ISSN 1434-1948,
Full text not available from this repository. (Request a copy)Abstract
First examples of the coordination chemistry of the As4S3 cage were obtained from solutions of As4S3 center dot M(CO)(5) (M = Cr, W) in CH2Cl2 and CuCln in CH3CN (n = 1) or CH3OH (n = 2) through interdiffusion techniques. The compounds (As4S3)(CuCl)(n) (1: n = 1; 2: n = 2) exhibit Cu coordination exclusively through the sulfur bridges. The crystal structure of 1 contains a saw-like (1)(infinity)[CuCl] backbone to which As4S3 cages are alternately fixed on both sides through two of their sulfur atoms. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURE; ETA(1)-P-BASAL COORDINATION; MAGNETIC-BEHAVIOR; BUILDING-BLOCK; SE MOLECULES; P4X3 X; COMPLEXES; CHEMISTRY; P4S3; FRAGMENTATION; Arsenic; Sulfur; Copper; Halides; Coordination modes; Solid-state structures |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Oct 2020 09:56 |
| Last Modified: | 14 Oct 2020 09:56 |
| URI: | https://pred.uni-regensburg.de/id/eprint/29954 |
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