Boncina, Matjaz and Apelblat, Alexander and Barthel, Josef and Bester-Rogac, Marija (2008) Investigation of the Dissociation and Dimerization of Cyclamic Acid in Aqueous Solutions by Means of a Conductometric Method. JOURNAL OF SOLUTION CHEMISTRY, 37 (11). pp. 1561-1574. ISSN 0095-9782,
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The electrical conductivity of aqueous cyclamic acid was studied in the concentration range (0.0004 < c/mol.dm(-3) < 0.14) at temperatures ranging from 278.15 to 303.15 K. Conductivities were measured by a precise method and examined by applying extended conductivity equations taking into account dimerization and incomplete electrolyte dissociation. Limiting molar electrolyte and ionic conductivities, dissociation and dimerization constants, and thermodynamic functions associated with dissociation and dimerization of cyclamic acid are discussed.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 25.0 DEGREES-C; ELECTROLYTE MIXTURES; CONDUCTANCE MEASUREMENTS; IONIZATION-CONSTANTS; CONDUCTIVITY; SODIUM; WATER; TEMPERATURES; CALIBRATION; ACESULFAME; Cyclamic acid; Conductivity; Thermodynamics; Electrolyte dissociation; Dimerization; Limiting electrolyte conductivities; Ionic conductivities; Dissociation constants; Dimerization constants |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Oct 2020 06:38 |
| Last Modified: | 21 Oct 2020 06:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/30118 |
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