Zabel, M. and Pavlovskii, V. I. and Poznyak, A. L. (2008) Barium (Nitrilotriacetato)oxalatocobaltate(III) Trihydrate Ba[Co(Nta)(C2O4)] center dot 3H(2)O: Crystal Structure. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 53 (10). pp. 1590-1595. ISSN 0036-0236, 1531-8613
Full text not available from this repository.Abstract
Crystals of Ba[Co(Nta)(C2O4)] center dot 3H(2)O were prepared, and their structure was solved by X-ray diffraction (monoclinic space group P2(1)/c), a = 10.0111(10) angstrom, b = 10.2838(6) angstrom, c = 14.2748(15) angstrom, beta = 100.350(12), Z = 4). The local environment of a Ba2+ ion includes two O atoms of water molecules and seven O atoms of the carboxyl groups of Nta(3-) and C2O42- ions of five complex anions. Honeycomb type layers can be distinguished in the crystal lattice; within the layers, each Ba2+ atom interacts with three complexes and vice versa. In addition, each Ba atom of the layer is bonded to complexes of the upper and lower layers. Thus, the crystal represents a three-dimensional coordination polymer.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Oct 2020 07:42 |
| Last Modified: | 23 Oct 2020 07:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/30258 |
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