Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II) complexes

Kozhevnikov, Valery N. and Shabunina, Olga V. and Kopchuk, Dmitry S. and Ustinova, Maria M. and Koenig, Burkhard and Kozhevnikov, Dmitry N. (2008) Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II) complexes. TETRAHEDRON, 64 (37). pp. 8963-8973. ISSN 0040-4020,

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Abstract

A wide series Of Substituted bipyridines were obtained through the synthesis of 1,2,4-triazines and their aza Diels-Alder reactions. The reported method facilitates the synthesis of functionally diverse bipyridines that provides fine-tuning of photophysical properties of new ligands and their Zn(II) and Ru(II) complexes. Some of substituted bipyridines exhibit 'off-on' fluorescence response toward Zn 2 cations. (C) 2008 Elsevier Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: SENSITIZED SOLAR-CELLS; RUTHENIUM(II); DYE; 1,2,4-TRIAZINES; TERPYRIDINE; LIGANDS; ANALOGS; LIGHT; 2,2 '-bipyridines; 1,2,4-triazines; luminescence
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 26 Oct 2020 07:11
Last Modified: 26 Oct 2020 07:11
URI: https://pred.uni-regensburg.de/id/eprint/30293

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