Ligand-centered oxidations and electron delocalization in a tetranuclear complex of a tetradonor-substituted olefin

Linseis, Michael and Winter, Rainer F. and Sarkar, Biprajit and Kaim, Wolfgang and Zalis, Stanislav (2008) Ligand-centered oxidations and electron delocalization in a tetranuclear complex of a tetradonor-substituted olefin. ORGANOMETALLICS, 27 (14). pp. 3321-3324. ISSN 0276-7333, 1520-6041

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Abstract

The tetrakis(4-styryl)ethene (TSTE4-)-bridged tet-raruthenium complex [[((PPr3)-Pr-i)(2)(CO)Cl center dot Ru}(4){mu(4)-(CH=CHC6-H-4)(4)(C=C)}] undergoes four consecutive oxidations at low potential. The ligand-dominated nature of these processes is confirmed by spectroscopic and quantum-chemical investigations.

Item Type: Article
Uncontrolled Keywords: ELECTROCHROMIC MATERIALS; COORDINATION-COMPLEXES; TCNE; CHEMISTRY; EXCHANGE; MAGNETS;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Prof. Dr. Rainer Winter
Depositing User: Dr. Gernot Deinzer
Date Deposited: 28 Oct 2020 07:19
Last Modified: 28 Oct 2020 07:19
URI: https://pred.uni-regensburg.de/id/eprint/30603

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