Kowalski, Konrad and Winter, Rainer F. (2008) The synthesis, structures, and electrochemistry of 1 '-heteroaryl-2,5-dimethylazaferrocenes. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 693 (12). pp. 2181-2187. ISSN 0022-328X, 1872-8561
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We report the synthesis of 1'-heteroaryl-2,5-dimethylazaferrocenes (heteroaryl = 2-bromothiophen-5-yl and 2-bromopyrid-6-yl) via palladium catalysed cross-coupling reactions along with their crystallographically determined structures. The newly synthesized compounds as well as the parent 2,5-dimethylazaferrocene have been investigated by cyclic voltammetry (CV) and were found to exhibit reversible first oxidations followed by an irreversible oxidation at considerably higher potential. (C) 2008 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CROSS-COUPLING REACTION; OLIGOTHIENYLFERROCENE COMPLEXES; COORDINATION CHEMISTRY; FERROCENE DERIVATIVES; METAL COMPLEXES; 2,5-DIMETHYLAZAFERROCENE; AZAFERROCENES; ELECTROPOLYMERIZATION; PHOSPHAFERROCENES; LITHIATION; azaferrocene; cross-coupling reaction; cyclic voltammetry; X-ray diffraction |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Prof. Dr. Rainer Winter |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Oct 2020 13:15 |
| Last Modified: | 29 Oct 2020 13:15 |
| URI: | https://pred.uni-regensburg.de/id/eprint/30829 |
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