Zabel, Manfred and Poznyak, A. L. and Pavlovskii, V. I. (2008) Crystal structure of barium bis[N-(2-hydroxyethyl)iminodiacetato]cobaltate(III) hydrocarbonate dihydrate Ba(mu(4)-HCO3)[trans(N)-Co(heida)(2)]center dot 2H(2)O. JOURNAL OF STRUCTURAL CHEMISTRY, 49 (3). pp. 575-579. ISSN 0022-4766, 1573-8779
Full text not available from this repository. (Request a copy)Abstract
Ba[Co(heida)(2)](HCO3)center dot 2H(2)O crystals were grown (orthorhombic, a = 9.4491(5) angstrom, b = 10.9719(5) angstrom, c = 19.6077(9) angstrom, Z = 4, space group Pca2(1)), and their structure was solved by X-ray diffraction. The Co atoms in the complex anion were coordinated by two N-(2-hydroxyethyl)iminodiacetate (heida) ligands via the N atom and two O atoms of each ligand. The Ba atoms and the complex anions form "honeycomb" layers linked via three O atoms. The "honeycombs" are additionally linked by their Ba atoms with the O atoms of the hydroxyethyl groups. The Ba atoms are aligned within a layer and linked via the bridging HCO3 hydrocarbonate groups. The c.n. of Ba atoms is 10 (one water molecule; five O atoms of the complex anions, one from each of the nearest neighbors; and four O atoms of the hydrocarbonate ions).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; crystal structure; cobalt(III) complex; barium hydrocarbonate; N-(2-hydroxyethyl)iminodiacetate ion |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 03 Nov 2020 10:21 |
| Last Modified: | 03 Nov 2020 10:21 |
| URI: | https://pred.uni-regensburg.de/id/eprint/30968 |
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