Short alpha/beta-peptides as catalysts for intra- and intermolecular aldol reactions

D'Elia, Valerio and Zwicknagl, Hans and Reiser, Oliver (2008) Short alpha/beta-peptides as catalysts for intra- and intermolecular aldol reactions. JOURNAL OF ORGANIC CHEMISTRY, 73 (8). pp. 3262-3265. ISSN 0022-3263,

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Abstract

Short alpha/beta-peptides, containing conformationally restricted cis-beta-aminocyclopropylcarboxylic acid units as turn-inducing elements, have been found to be efficient catalysts for inter- and intramolecular aldol reactions. The tripeptide H-(L)-Pro-triangle-(L)-Pro-OH was identified to perform especially well in homogeneous and heterogeneous aqueous solutions as well as in organic solvents.

Item Type: Article
Uncontrolled Keywords: AMINOCYCLOPROPANE-CARBOXYLIC-ACIDS; AMINO-ACIDS; ROBINSON ANNULATION; LINEAR PEPTIDES; WATER; PROLINE; CONDENSATION; ORGANOCATALYSIS; CONFORMATIONS; EFFICIENT;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 04 Nov 2020 07:45
Last Modified: 04 Nov 2020 07:45
URI: https://pred.uni-regensburg.de/id/eprint/31039

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