Kunkely, Horst and Vogler, Arnd (2008) Photochemical oxidative addition of hydrazinium cations to tetracyanoplatinate(II) induced by OSCT excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 11 (4). pp. 413-414. ISSN 1387-7003, 1879-0259
Full text not available from this repository. (Request a copy)Abstract
The hydrazinium cations N2H62+/N2H5+ form ion pairs with [Pt(CN)(4)](2-). Outer-sphere charge transfer excitation (Pt-II --> N2H62+/N2H5+) induces an oxidative addition: N2H62+/N2H5+ Pt(CN)(4)(2-) --> [Pt-IV(CN)(4)(NH3)(2) and [Pt(CN)(4)(NH3)(NH2)], respectively. (C) 2008 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SPECTROSCOPY; charge transfer; photochemistry; platinum; hydrazinium; oxidative addition |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 04 Nov 2020 16:10 |
| Last Modified: | 04 Nov 2020 16:10 |
| URI: | https://pred.uni-regensburg.de/id/eprint/31100 |
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