Intraligand fluorescence and phosphorescence of tris(pyrazolyl) hydridoborate complexes

Kunkely, Horst and Pawlowski, Valeri and Strasser, Andreas and Vogler, Arnd (2008) Intraligand fluorescence and phosphorescence of tris(pyrazolyl) hydridoborate complexes. INORGANIC CHEMISTRY COMMUNICATIONS, 11 (4). pp. 415-417. ISSN 1387-7003,

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Abstract

The complexes GdTP3 and PPh(3)AgTp with Tp = Hydridotris(I-pyrazolyl) borate in the solid state are characterized by rather similar luminescence spectra which consist of a fluorescence near 390 nm and a phosphorescence near 480 nm. These emissions originate from a Tp(-) pi pi * IL singlet and triplet, respectively. Owing to the heavy-atom effect of Gd and Ag the phosphorescence appears also at rt. (C) 2008 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: PYRAZOLE-DERIVED LIGANDS; AMBIENT CONDITIONS; CHARGE-TRANSFER; COORDINATION CHEMISTRY; OPTICAL-PROPERTIES; PHOTOCHEMISTRY; DERIVATIVES; MODEL; fluorescence; phosphorescence; silver(I); gadolinium(III); hydrotris(1-pyrazolyl)borate
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Depositing User: Dr. Gernot Deinzer
Date Deposited: 04 Nov 2020 16:11
Last Modified: 04 Nov 2020 16:11
URI: https://pred.uni-regensburg.de/id/eprint/31101

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