Zabel, M. and Poznyak, A. L. and Pavlovsky, V. I. (2008) Crystal Structure of (1,10-phenanthroline)ethylenediamine-N,N'-diacetatocopper(II) pentahydrate, [Cu(Edda)(Phen)] center dot 5H(2)O. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 34 (2). pp. 97-101. ISSN 1070-3284, 1608-3318
Full text not available from this repository. (Request a copy)Abstract
The products of oxidation of ethylenediaminetetraacetic acid by manganese dioxide have been used to synthesize crystals of [Cu(Edda)(Phen)] center dot 5H(2)O (Edda is ethylenediamine-N,N'-diacetate, and Phen is 1,10-phenanthroline). The X-ray diffraction analysis of the crystals shows that the N atoms of the Edda and Phen ligands lie in the equatorial plane around the Cu atom, and the 0 atoms of the Edda ligands are localized in more remote axial positions. The [Cu(Edda)(Phen)] complexes are grouped in pairs at a distance of 3.46 angstrom between the mean planes of the Phen ligands. Ten water molecules are united by hydrogen bonds into symmetric isolated clusters, and further they form a three-dimensional framework with the [Cu(Edda)(Phen)] complexes.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | (H2O)(8); COMPLEX; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Nov 2020 07:56 |
| Last Modified: | 10 Nov 2020 07:56 |
| URI: | https://pred.uni-regensburg.de/id/eprint/31486 |
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