Tetrakis(triphenylarsine)copper(I) hexafluoridophosphate

Kern, Thomas and Knoer, Guenther and Zabel, Manfred and Monkowius, Uwe (2008) Tetrakis(triphenylarsine)copper(I) hexafluoridophosphate. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64. M99-U957. ISSN 1600-5368,

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Abstract

In the crystal structure of the title compound, [Cu(C18H15As)(4)]PF6, the Cu atom is coordinated by four As atoms of triphenylarsine ligands in a tetrahedral geometry. The complex cation is located on a crystallographic threefold axis. Both PF6- anions are located on special positions of site symmetry (3) over bar. The Cu-As bond of the independent arsine ligand is shorter than the Cu-As bonds of the three symmetry-related arsine ligands.

Item Type: Article
Uncontrolled Keywords: CRYSTAL-STRUCTURE DETERMINATIONS; LEWIS-BASE ADDUCTS; METAL(I) COMPOUNDS; TETRAKIS(TRIPHENYLPHOSPHINE)-COPPER(I);
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Central Analytical Services
Depositing User: Dr. Gernot Deinzer
Date Deposited: 11 Nov 2020 06:33
Last Modified: 11 Nov 2020 06:56
URI: https://pred.uni-regensburg.de/id/eprint/31516

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