Monkowius, Uwe and Ritter, Stefan and Koenig, Burkhard and Yersin, Hartmut and Zabel, Manfred (2008) {Bis[2-(diphenylphosphanyl) phenyl] ether-k(2)P,P '}(1,1 '-dibenzyl-1H, 1 ' H-4,4 ' bi-1,2,3-triazole-k(2)N(3), N-3 ') copper(I) hexafluoridophosphate dichloromethane hemisolvate. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64. M195-U1881. ISSN 1600-5368,
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In the crystal structure of the title compound, [Cu(C18H16N6)(C36H28OP2)] PF6 center dot 0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)] PF6 center dot 0.5CH(2)Cl(2) {DPEPhos = bis[(diphenylphosphanyl) phenyl] ether and Bn- bta = 1,1 '-dibenzyl-1H, 1 ' H- 4,4 '-bi-1,2,3triazole}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetrahedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 11 Nov 2020 07:01 |
| Last Modified: | 11 Nov 2020 07:01 |
| URI: | https://pred.uni-regensburg.de/id/eprint/31518 |
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