Schwan, Karl-Christian and Adolf, Ariane and Bodensteiner, Michael and Zabel, Manfred and Scheer, Manfred (2008) Synthesis and crystal structures of novel copper(I) complexes of a phosphanylborane. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 634 (8). pp. 1383-1387. ISSN 0044-2313,
Full text not available from this repository. (Request a copy)Abstract
The novel copper iodide clusters [Cu-3(mu-I)(mu(3)-I)(2)(PH2BH2 center dot NMe3)(3)] (2) and [Cu-4(mu-I)(2)(mu(3)-I)(2)(PH2BH2 center dot NMe3)(3)] (3) were synthesized by treating CuI with the primary phosphine (H2PBH2 center dot NMe3). The novel features of both compounds, which have been characterized by X-ray crystallography, are the unsymmetrical constitution of the copper iodide core due to the influence of the monodentate phosphorus ligand. This results in copper atoms with different coordination numbers within the compound. Complex 2, the major product of the reaction, contains a distorted octahedral Cu3I3-core, in which one vertex is missing. Complex 3 was isolated as a by-product and is composed of a Cu4I4-core in a distorted octahedral coordination.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ONE-DIMENSIONAL POLYMERS; PHOSPHORUS-BORON BONDS; MONOMERIC PHOSPHINOBORANES; CATALYZED FORMATION; PHOSPHINE-BORANES; CHEMISTRY; IODIDE; PENTAPHOSPHAFERROCENE; CLUSTERS; LIGANDS; boron; phosphorus; copper; iodide; cluster compounds |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Nov 2020 12:59 |
| Last Modified: | 24 Nov 2020 12:59 |
| URI: | https://pred.uni-regensburg.de/id/eprint/31787 |
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