Monkowius, U. and Svartsov, Y. N. and Fischer, T. and Zabel, M. and Yersin, H. (2007) Synthesis, crystal structures, and electronic spectra of (1,8-naphthyridine)Re-I(CO)(3)Cl and [(1,8-naphthyridine)Cu-I(DPEPhos)]PF6. INORGANIC CHEMISTRY COMMUNICATIONS, 10 (12). pp. 1473-1477. ISSN 1387-7003,
Full text not available from this repository. (Request a copy)Abstract
Two 1,8-naphthyridine (nap) metal complexes (nap)Re-I(CO)3CI (1) and [(nap)Cu-I(DPEPhos)]PF6 (2) were synthesized and characterized by NMR-, emission, and absorption spectroscopy, elemental analysis, mass spectrometry, and X-ray structural analysis. In both complexes, the nap ligand coordinates with both N atoms to the metal centre in a bidentate manner. I and 2 exhibit a broad phosphorescence in solid state at T = 300 K, which is completely quenched in solution at r.t. In addition, the gas-phase structures of both complexes were optimized at the B3LYP/6-31G(d,p) level of theory. (c) 2007 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CU-I COMPLEXES; 1,8-NAPHTHYRIDINE-BASED DINUCLEATING LIGANDS; METAL-PERCHLORATE COMPLEXES; FLUXIONAL BEHAVIOR; ELECTROCHEMICAL PROPERTIES; DIRHODIUM(II) COMPLEX; EMISSION PROPERTIES; DIIRON COMPLEXES; EXCITED-STATE; NAPY; naphthyridine; rhenium; copper; electronic spectra; photoluminescence |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 25 Nov 2020 08:23 |
| Last Modified: | 25 Nov 2020 08:23 |
| URI: | https://pred.uni-regensburg.de/id/eprint/31846 |
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