Scheer, Manfred and Schindler, Andrea and Merkle, Roger and Johnson, Brian P. and Linseis, Michael and Winter, Rainer and Anson, Christopher E. and Virovets, Alexander V. (2007) Fullerene C-60 as an endohedral molecule within an inorganic supramolecule. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129 (44). 13386-+. ISSN 0002-7863,
Full text not available from this repository. (Request a copy)Abstract
C-60 subset of[Cu26Cl26L2{Cp*Fe(P-eta 5-(5))}(13)(CH3CN)(9)] (L = H2O) represents a first example of a complete encapsulation of C-60 itself by an inorganic fullerene-like system via molecular recognition of the five- and sixfold-symmetric structural motif of C-60. The product exhibits an inorganic cover consisting of 99 inorganic core atoms from pentaphosphaferrocene and Cu(I) chloride building blocks. This is the first instance of a hollow structure that completely encapsulates C-60. The overall spherical molecule possesses an outer diameter of 2.3 nm and shows a remarkable electronic interaction between C-60 and the encapsulating giant molecule.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PENTAPHOSPHAFERROCENE; CATIONS; ANIONS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 30 Nov 2020 07:22 |
| Last Modified: | 30 Nov 2020 07:22 |
| URI: | https://pred.uni-regensburg.de/id/eprint/31930 |
Actions (login required)
 |
View Item |
