Kunkely, Horst and Vogler, Arnd (2007) Generation of nitric oxide by photolysis of silver hyponitrite in suspension induced by LMCT excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 10 (11). pp. 1294-1296. ISSN 1387-7003,
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The yellow colour of silver hyponitrite is attributed to a LMCT band at lambda(max) = 419 nm. Solid A(2)N(2)O(2) and its suspensions in water or acetonitrile are light sensitive. LMCT excitation leads to a photolysis according to the equation Ag2N2O2 -> 2Ag + 2NO. In the presence of air and water, NO is finally converted to HNO2. (c) 2007 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CHARGE-TRANSFER STATE; OPTICAL-PROPERTIES; AQUEOUS-SOLUTION; METAL; LIGAND; NO; LUMINESCENCE; INTRALIGAND; COMPLEXES; CHEMISTRY; electronic spectra; LMCT; hyponitrite complexes; silver complexes; photochemistry; nitric oxide |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 30 Nov 2020 10:41 |
| Last Modified: | 30 Nov 2020 10:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/31976 |
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